In ventoy there are 3 ways to boot.1. Add the iso and see if it works. 2. Add the iso and create a folder called ventoy on the root of your USB and create a ventoy. json file there to include -" "auto_memdisk": [ "/ISO/Win10XPE.iso" ]}save it and it will boot through memdisk, takes a bit longer though especially for large isos. 3. You can extract the boot.wim from the iso then rename it, need the ventoy_wimboot.img from the ventoy site for that, just drop it in a folder called ventoy on the root of you USB.