For Copy to USB-Device plugin, Add Grub2-EFI (x64 UEFI only) is only an option for multi-boot, to be safer, do not use it at first
For copy to USB or Copy to USB-Device BCD, the default options are OK with BootIce + FAT32.
To boot from an USB stick, Fast Boot should be disabled a priori. It may depends on PC manufacturer!